According to police, Rowland approached Josephson about 2:09 a.m. Friday morning outside a bar on Harden Street in the Five Points nightspot of Columbia.
Ms Josephson's body was discovered with wounds to her head, neck, face, upper body, leg and foot, according to arrest warrants. She simply mistakenly got into this vehicle thinking it was an Uber ride'.
The police have not yet revealed how Samantha was killed by Nathaniel David Rowland.
Fielding Pringle, the public defender for Rowland, said Sunday she has no statement on behalf of her client at this time.
"We believe. that she simply mistakenly got into this particular vehicle thinking it was an Uber ride", Holbrook said of Josephson, noting that surveillance video captured her getting into the auto.
Richardson says it's not clear when Rowland's next court appearance will be.
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Her friends called the authorities to report a missing person about 12 hours later after they had not seen Josephson since she left the bar the night before, he said.
According to jail logs, Rowland has been given an $872.50 personal recognizance bond on the failure to stop on police command and drug possession charge but remains in jail on the two more serious charges of kidnapping and murder.
Chief Holbrook said police had spoken with Ms Josephson's family and would support them as the case continued. There is nothing tougher than to stand before a family and explain how a loved one was murdered,"he said".
Josephson hopped into a black Chevy Impala, thinking it was her ride and about 14 hours later turkey hunters found her body in a field in Clarendon County, about 90 miles from Columbia, he said.
"There are no words to describe the huge pain, his actions have caused our family and friends".
"It's only one ME", he wrote in one of the posts.
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Samantha's father Seymour Josephson confirmed his daughter's death in a Facebook post on Saturday, writing, "It is with tremendous sadness and of a broken heart that I post this!"
Around 3 a.m. Saturday: A Columbia police officer observed a matching Impala just blocks away from Five Points, Holbrook said.
After a frantic day of searching for the missing student the school had earlier confirmed she was dead. I will miss and love my baby girl for the rest of life. It is extremely hard to write this and post it but I love her with all my heart.
"I can't tell you how painful this is", he said.
Josephson was a native of Robinson Township, New Jersey. Her cellphone was also found in the vehicle.
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